Hilary Duff is The CW's newest "Gossip Girl."
The network confirmed to Access Hollywood on Wednesday that the singer-actress is joining the show's cast for its upcoming third season. She's set to debut in the fourth episode on October 5.
VIEW THE PHOTOS: XOXO! Hot Shots From 'Gossip Girl'
According to Entertainment Weekly, who was first to report the casting, Hilary will play Olivia Burke, a movie star who retreats from the limelight for a "traditional college experience" at NYU, where she'll room with Vanessa (Jessica Szohr).
That may not be the third season's only odd college pairing – the second season concluded with Georgina Sparks (Michelle Trachtenberg) requesting to room with frenemy Blair Waldorf (Leighton Meester) at the New York school.
VIEW THE PHOTOS: Young Hollywood
Hilary had an opening in her schedule after NBC turned down her pilot, "Barely Legal."
"Gossip Girl" returns to The CW this September.
Related Content from AccessHollywood.com:
VIEW THE PHOTOS: Hilary Duff
PLAY IT NOW: Chace Crawford Talks 'Footloose' Remake, 'Gossip Girl' & More
PLAY IT NOW: Nancy O'Dell & Friends Support The Runway For Life Benefit
MORE ACCESS ON THESE TOPICS: Hilary Duff - Gossip Girl - Casting Call - Young Hollywood - Celebrities
